Define lineshape function such that gives the probability that a transition between two levels is an emission (or absorption) of photon whose frequency lies in the range and . Normalization demands
If is the number of atoms in a given energy level, the spectral distribution of population in the level is given by , i.e., is the number of atoms in the levels within frequency range and , so that
Using the above, one can rewrite the equation defining Einstein's A - coefficient for spontaneous emission