Module 4 : Kinetic Theory of Gases

Lecture 5 : Maxwell-Boltzmann Velocity Distribution

and 

(4.87)

where is the constant of integration. The symmetry provides the same integration constant for all the three equations.
Substituting the expressions for   and   in Eq.(4.73),

(4.88)

(4.89)

or,

(4.90)

where 

(4.91)

The density is found to be a function of v only, and it is maximum at the origin where v = 0 and falls off exponentially with v2 (Fig. 4.13). To calculate the number of molecules with speeds between v and v + dv,  the volume of the spherical shell of thickness dv at a distance v from the origin is multiplied by the density of points , so that


Fig.4.13 Density of velocity points

(4.92)

Substituting for ρ from Eq. (4.91), the total number of molecules


(4.93)

 

(4.94)