Module 4 : Kinetic Theory of Gases

Lecture 5 : Maxwell-Boltzmann Velocity Distribution

(4.75)

At a radial distance v from the origin,

constant

(4.76)

(4.77)

To solve the Eq.(4.75) subject to the constraint of the equation (4.64), Lagrange’s method of undetermined multipliers is applied. Multiplying Eq.(4.77) by λ and adding to Eq.(4.75),

(4.78)

where λ is called the Lagrange’s  multipliers.

 Since vx, vy and vz are now independent variables, the coefficients of dvx, dvy and dvz are individually equated to zero.

(4.79)

(4.80)

(4.81)

From Eq.(4.79),

(4.82)

(4.83)

(4.84)

or,            

(4.85)

Similarly,

(4.86)