Module 4 : Kinetic Theory of Gases

Lecture 5 : Maxwell-Boltzmann Velocity Distribution

where f(vx) is called the distribution function for x -component of velocity.
Similarly,

(4.67)

and  

(4.68)

(4.69)

Some of the molecules of have y -component velocities lying between vy and vy + dvy and let this be represented by . A differential of second order  has been used, since this is a small fraction of an already small fraction, but still large enough to contain many molecules. Since the number of molecules is large, the following relation holds good.

(4.70)

(4.71)

Similarly, represent the number of molecules whose velocity components would lie between vx and vx + dvx, vy and vy + dvy and vz and vz + dvz. Therefore,

(4.72)

The number of representative points per unit volume, or the density of point in velocity space, represented by ρ, is


(4.73)

Since the velocity distribution is isotropic, the density is the same in any volume element so that

(4.74)