Module 2 : Heterogeneous catalysis

Lecture 25 : Catalyst Deactivation

 

Now ,

Hence substituting for

 

 

 

 

 

(8)


τw is called the weight time similar to space-time τ. CA and a' vary with time.

Substituting, in equation (8)

Plotting versus ‘t' gives a straight line of slope of -kd and intercept In (kτw)

Fig. 1. Plot to determine the rate constant and the deactivation rate constant for a reaction over deactivating catalyst. ( For mixed reactor, constant flow and independent deactivation)