Module 1 : Atomic Structure
Lecture 3 : Angular Momentum
 
   The conventional symbol used for f() is (), is Greek symbol for capital theta, and we will stick to this convention as it will help you when you refer to other books. Similarly denotes a function of , ( ).
    Seperating the variables, (, ) = () ().
  ( L 2 / 2I ) = E
Substituting
^ 2 = -2IE/ 2 (3.15)

= [(1/sin 2) 2 / 2 + (1/sin) / sin /]

 
= (1/sin 2) ( 2 / 2)+ (1/sin ) / sin / (3.16)

Dividing by Q , multiplying by sin2 and rearranging,

 
1/ 2/2 = -1/ sin /sin / - 2IE/ 2 sin 2 (3.17)

we see that the left hand side depends only on and the right hand side depends only on . Since and are independent, each side must be equal to the same constant. Calling this constant – ml2 we get

 
2/ 2 = –ml2 (3.18)

setting x = cos, sinbecomes = (1-x 2 ) 1/2

Setting 2IE / 2 = l ( l +1 )

And by using (3.18), (3.17) becomes
 
(1-x 2 ) d 2 /d2– 2xd /d +{ l ( l +1) – ml 2 / (1- x 2 ) } = 0 (3.19)

This is called the associated Legendre equation. The solutions for this equation are “well behaved” (ie, single valued, differentiable and finite) for the following conditions

a) l = 0,1,2,……
 
b) 1 m l l (3.20)

This implies that only when l is a positive integer and the absolute value of ml is less than or equal to the value of l , acceptable or well behaved solutions exist. The normalized solutions for equation (3.15) for l = 0, 1 and 2 are given in the Table 3.1. Substitute the first three solutions in eq (3.15) and verify that these satisfy the equation.

 

Table 3.1 A few normalized solutions to equation 3.15. The literature symbol for these solutions is Y l m ( , ) , and for simplicity, we take m = ml .

 

l

m = m l

Y lm ( , )

0

0

(4 ) -1/2

1

0

(3/4 ) 1/2 cos

1

1

( 3/8 ) 1/2 sin e i

2

0

(5/16 ) 1/2 (3 cos 2 - 1)

2

1

(15/16 ) 1/2 cos sin e i

2

2

(15 / 32 ) 1/2 sin 2 e 2 i