4. Thermocouple
Thermocouple works on the fact that when a junction of dissimilar metals heated, it produces an electric potential related to temperature. As per Thomas Seebeck (1821), when two wires composed of dissimilar metals are joined at both ends and one of the ends is heated, then there is a continuous current which flows in the thermoelectric circuit. Figure 2.5.5 shows the schematic of thermocouple circuit. The net open circuit voltage (the Seebeck voltage) is a function of junction temperature and composition of two metals. It is given by,
ΔVAB = αΔT (2.5.2)
Where α, the Seebeck coefficient, is the constant ofproportionality.

Figure 2.5.5 Schematic of thermocouple circuit
Generally, Chromel(90% nickel and 10% chromium)–Alumel(95% nickel, 2% manganese, 2% aluminium and 1% silicon) are used in the manufacture of a thermocouple. Table 2.5.1 shows the various other materials, their combinations and application temperature ranges.