Module 5 : Statistical Thermodynamics

Lecture 1 : Fundamentals

Wave particle duality

de Broglie equation

de Broglie equation relates the momentum of the photon ( or electron) with its wave length, representing the wave-particle duality. The total energy ε and mass of a moving particle m are related by Einstein's famous equation,

E = mc2

(5.5)

where c is the velocity of light ( 3 X 108 m/s). For a photon ( photon does not have mass but has momentum) of electromagnetic radiation, Planck's equation gives,

ε = hv

(5.6)

where h is the Planck's constant and v is the frequency of the wave.

Now momentum p of the photon is

(5.7)

When this equation is applied to a heavy particle, the wavelength is so small that the modification made on rectilinear motion by the wave can be neglected, thus reverting back to classical mechanics.