Module 1 : Classical Thermodynamics

Lecture 6 : Thermodynamic Relations - II

SECOND T - dS RELATION

Again, let us consider

S = S(T, p)

1.119


1.120

Now,

1.121

where, Cp is the heat capacity at constant pressure (kJ/K).

Therefore, applying Maxwell's fourth relation,

1.122

This is known as 2nd T - dS relation.