Module 5 : Statistical Thermodynamics

Lecture 5 : Fermi-Dirac statistics

Calculation of εm0

The energy and momentum of a particle are related by equation

(5.123)

The maximum momentum Pm0 corresponds to the maximum m0 by the equation

(5.124)

At absolute zero, The momentum space is uniformly populated with a sphere of radius Pm0 and there are no points outside the sphere. The total number of electron N is

(5.125)

Therefore,

(5.126)

and

(5.127)

where h and m are Plank's constant and mass of an electron, respectively.

The maximum K.E. of free electron is having some finite value. But as per M - B statistics average K.E. of gas molecules is , and same in zero at absolute zero temperature. Thus, the concept of absolute zero as a state in which all molecular or electronic motion has ceased is not correct. as it is revealed by F - D statistics.
At temperatures other than absolute zero εm is calculated from

(5.128)

when T = 0 K, εm = εm0

Velocity Distribution Function

To obtain the velocity distribution function substitute in Eq. (5.119) for dpx, dpy, dpz

(5.129)

where

Since distribution is spherically symmetrical,

 

 

(5.130)

At T = 0 K

 

(5.131)

and

Figure 5.5 shows the velocity distribution functions of v and ε at T = 0 K and at two higher temperatures.

Fig 5.5 Velocity distribution in Fermi-Dirac Statistics