Module 11 : Transition Metal Catalysis

Lecture 35 : Nickel Catalysts

 

Examples:

K. Shibata, M. Kimura, M. Shimizu, Y. Tamaru, Org. Lett. 2001 , 3 , 2181.

M. Lozanov, J. Montgomery, J. Am. Chem. Soc. 2002 , 124 , 2106.

•  E. Greene, J. P. Lansard, J. L. Luche, C. Petrier, J. Org. Chem. 1984 , 49 , 931.
 

11.9.3.7 Cycloaddition

The most widely used application of the nickel-diene complex is the different mode of coupling of 1,3-dienes, including dimerization, trimerization and oligomerization (Scheme 16).

Scheme 16