Module 4 : Chemical and non–chemical approach to materials synthesis - part 2

Lecture 26 : Chemical Vapor Deposition

• Chemical vapor deposition (CVD) is widely used for depositing thin films of a large variety of materials. Applications of CVD range from the fabrication of microelectronic devices to that of the deposition of protective coatings.

• In a typical CVD process, reactant gases at room temperature enter the reaction chamber. The gas mixture is heated as it approaches the deposition surface, heated radiatively or placed upon a heated substrate.

• Depending on the process and operating conditions, the reactant gases may undergo homogeneous chemical reactions in the vapor phase before striking the surface.

• Near the surface thermal, momentum, and chemical concentration boundary layers form as the gas stream heats, slows down due to viscous drag, and the chemical composition changes.

• Heterogeneous reactions of the source gases or reactive intermediate species (formed from homogeneous pyrolysis) occur at the deposition surface forming the deposited material. Gaseous reaction by-products are then transported out of the reaction chamber.