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Electron in a Periodic Potential |
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Inside a lattice the electron is subjected to a periodic potential, i.e., the form potential repeats itself in space. Thus if is the inter-atomic distance in a one dimensional lattice, we have |
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For potentials that are periodic, the wavefunction satisfies Bloch theorem which states that the form of the wavefunction is |
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where is a periodic function with the same periodicity as that of the lattice, i.e., |
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Substituting this in Schrödinger equation for , we would obtain an equation for which must be solved. |
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A simple model often used to mimic the periodic potential is known as the Krönig-Penny model , the form of which is shown in the figure. |