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We have seen that the solution of the Schrödinger equation for an arbitrary value of is a plane wave . This, however, is not true at the zone boundary where Bragg reflection takes place. At such a boundary the wave function has two components, viz., and . One can form two standing waves using these two wavefunctions, viz., and . The corresponding electron densities are proportional to and . These two densities have their maxima respectively at the locations of the atoms and midway between atoms, as shown. |