Module 5 : Electrochemistry
Lecture 23 : Batteries and Fuel Cells
 
A few other common cells will now be outlined.
Miniature flat and round cells, capable of delivering 1.5 V, are used in calculators, hearing aids etc. In the alkaline manganese cell, zinc is the anode, a mixture of MnO2 and graphite is the cathode and the electrolyte is a solution of KOH contained in an absorbent material. The overall cell reaction is :
 
Zn( s) + 2MnO2 (s) + H2O ZnO + H2O + 2 MnO (OH)
 

The silver oxide-Zn cell, though costlier, lasts for a longer time. Here the anode is Zn, cathode is Ag2O and the electrolyte is the KOH (aq). The cell reaction is:


Zn + AgO + H2O ZnO + H2O + Ag