Module 4 : Solid State Chemistry
Lecture 16 : Lattices and Unit Cells
 

In the following table (16.3), we list some common substances which are found in the 14 Bravais lattices. How a given substance chooses to be found in a given lattice type is determined by the sizes of the constituent particles and the detailed interactions between them.

 

Table 16.3 Common substances in seven crystal systems.

 

1

     Cubic

Metal like Ni, Ag, Au, Cu, Al; Na+ ions in NaCl lattice [FCC] one form of Fe, V, Cr, Mo, W; CsCl, taking Cs+ and Cl - together [BCC], - Polonium, Cl- lattice in a CsCl lattice [simple cubic]

2

Hexagonal

Metallic Be, SiO2, Mg2SiO4, corundum, quartz, ruby

3

Orthorhombic

Epsom salts, ancylite, sulphur, pyrite, Hg(II)chloride

4

Tetragonal

Zircon, Tellurium oxide, PbTiO3

5

Triclinic

Pentahydrate form of Cu (II) sulphate, serandite, feldspar, n- alkanes, lysozyme crystals grown at pH 4.5

6

Mono clinic

Gypsum, sulphur, jadite, nephrite, K3Fe(CN)6 Hg(II) chloride, potassium chlorate

7

Rhombohedral

La cerite, dolomite, calcite, ruby, MgCO3