Module 2 : Phase Transitions

Lecture 4 : Mixture of variable composition

Ref. to  Eq. (2.41), we can write in a similar manner,

G = G(p,T,n1,n2,...........,nk)

(2.49)

or,


(2.50)



(2.51)

Since,

G = U +pV - TS

(2.52)


(2.53a)

or,


 


(2.53b)

Comparing Eq. (2.47)  and  Eq.(2.51), we get,

(2.54)


(2.55)

Eq. (2.51) can be written as

(2.56)