ΣWcycle = ΣQcycle |
1.8 |
or,
WA + WB = QA + QB |
1.9 |
or,
QA - WA = -(QB - WB) |
1.10 |
From Eqs. (1.6) and (1.7), it yields
ΔEA = -ΔEB |
1.11 |
similarly, had the system returned from state 2 to state 1 by following the path C instead of path B,
ΔEA = -ΔEC |
1.12 |
From Eqs. (1.11) and (1.12),
ΔEB = ΔEC |
1.13 |
Thus, it is seen that the change in energy between two states of a system is the same, whatever path the system follow in undergoing the change of state. Therefore, energy has a definite value for energy state of the system. Hence it is a point function and is a property of the system. The energy is an extensive property. The specific energy
(J/kg) is an intensive property. The cyclic integral of any thermodynamic property is zero (∫dE = 0).