Module 5 : Modern Characterization of materials

Lecture 36: X- Ray Photoelectron Spectroscopy (XPS)

Cylindrical Mirror Analyzer (CMA)

• The electrons ejected will pass through a device called a CMA.

• The CMA has two concentric metal cylinders at different voltages.

• One of the metal cylinders will have a positive voltage and the other will have a 0 voltage. This will create an electric field between the two cylinders.

• The voltages on the CMA for XPS and Auger e- s are different.

• When the e- s pass through the metal cylinders, they will collide with one of the cylinders or they will just pass through.

• With a change in cylinder voltage the acceptable kinetic energy will change and then you can count how many e- s have that KE to reach the detector.