Module 1 : Introduction

Lecture 4 : Multilayer adsorption & pore condensation

Now,

Substituting this in equation [2]

Or

Or --------------------[3]

The Eq. 3 is known as the BET equation for multilayer adsorption. This equation can explain type II isotherm.

Table 1. Isotherms most commonly used in catalysis

Type

Isotherm equations

Type of adsorption

Langmuir

Chemisorption

Physisorption

Freundlich

Chemisorption and physisorption at low coverage

Temkin

Chemisorption

Brunauer-Emmet-Teller

Multilayer physical adsorption