Now,
Substituting this in equation [2]
Or
Or --------------------[3]
The Eq. 3 is known as the BET equation for multilayer adsorption. This equation can explain type II isotherm.
Table 1. Isotherms most commonly used in catalysis
Type |
Isotherm equations |
Type of adsorption |
Langmuir |
Chemisorption Physisorption |
|
Freundlich |
Chemisorption and physisorption at low coverage |
|
Temkin |
Chemisorption |
|
Brunauer-Emmet-Teller |
Multilayer physical adsorption |