Module 4 : Solid State Chemistry
Lecture 17 : Closed Packed Structures
  17.5

Problems

17.1) For the tetragonal ( four spheres whose centers coincide with the corners of a square and which are such that each sphere is touching two adjacent spheres ) and pentagonal coordination, estimate the critical radius ratios for the spheres that can be accommodated in the void space available. Treat the problem as a planar problem as this is much simpler .

 

17.2) We have given a few examples of triangular, cubic and other coordinations. From web-sites / literature, give another distinct example for each one of these coordinations.


17.3) When we go from planar to non - planar coordination in exercise 17.1 above, does the critical radius ratio increase or decrease ?
 
17.4) Find the critical radius ratio for cubic coordination.