Module 3 : Molecular Spectroscopy
Lecture 12 : Electronic Spectroscopy
 

In Fig. 12.1, the thick lines represent electronic energy levels which are separated from one another by energies in the range of 0.5 to a few electron volts. “Within” (or between two) each electronic energy levels there are several vibrational energy levels and within each vibrational level, there are several rotational energy levels. These energy levels are not equally placed and the spacings between higher levels decrease. The range of energy levels and the region of the electromagnetic radiation that causes transitions between these levels is shown in Table 12.1

Table 12.1 Molecular Energy levels and the Regions of Electromagnetic Radiation

Region of the
Spectrum

Frequency
Range (Hz)

Wavelength Range

Energy range

Kind of
Spectroscopy

X-rays

3 x 10 16 to 3x10 18

10nm to 100pm

~10 4 kJ/mol

X-ray photo-electron
Spectroscopy (inner
electrons)

Visible and UV

3x1014 to 3x1016

1µm to 10nm

~10 2 kJ/mol

Electronic Spectroscopy

Infrared

3x10 12 to 3x10 14

100µm to 1µm

~10 kJ/mol

Vibrational Spectroscopy

Microwave

3x10 10 to 3x10 12

1cm to 100µm

100J/mol

Rotational Spectroscopy

Radio frequency

3x10 6 to 3x10 10

10m to 1 cm

0.001 to 10J/mol

Magnetic Resonance Spectroscopy