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In Fig. 12.1, the thick lines represent electronic energy levels which are separated from one another by energies in the range of 0.5 to a few electron volts. “Within” (or between two) each electronic energy levels there are several vibrational energy levels and within each vibrational level, there are several rotational energy levels. These energy levels are not equally placed and the spacings between higher levels decrease. The range of energy levels and the region of the electromagnetic radiation that causes transitions between these levels is shown in Table 12.1
Table 12.1 Molecular Energy levels and the Regions of Electromagnetic Radiation
Region of the
Spectrum |
Frequency
Range (Hz) |
Wavelength Range |
Energy range |
Kind of
Spectroscopy |
X-rays |
3 x 10 16 to 3x10 18
|
10nm to 100pm |
~10 4 kJ/mol |
X-ray photo-electron
Spectroscopy (inner
electrons) |
Visible and UV |
3x1014 to 3x1016 |
1µm to 10nm |
~10 2 kJ/mol |
Electronic Spectroscopy |
Infrared |
3x10 12 to 3x10 14 |
100µm to 1µm |
~10 kJ/mol |
Vibrational Spectroscopy |
Microwave |
3x10 10 to 3x10 12 |
1cm to 100µm |
100J/mol |
Rotational Spectroscopy |
Radio frequency |
3x10 6 to 3x10 10 |
10m to 1 cm |
0.001 to 10J/mol |
Magnetic Resonance Spectroscopy |
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