Module 1:Steelmaking Fundamentals
  Lecture 6: Steel Making Reactions: Oxidation of Iron and Silicon
 

 

Iron Oxidation:

Oxidation of iron i.e. reaction 1 is the most important since it controls

  • FeO content of slag and oxygen content of steel
  • Loss of iron in slag and hence affects productivity
  • Oxidation potential of slag

In addition to the above FeO also helps in dissolution of lime in slag.
Consider the reaction


The equilibrium constant  is

(6)

h is henrian and a is raoultian activity.  Since Fe in steel is pure; , and

 


(7)


(8)

In equation 8, T is in K. By equations 6, 7 and 8 we get

 
(9)