Module 1:Steelmaking Fundamentals
  Lecture 6: Steel Making Reactions: Oxidation of Iron and Silicon
 


What are the oxidation reactions?

The principle reactions in steelmaking comprise of oxidation of impurity elements by oxygen dissolved in hot metal or FeO content of slag.

(1)
(2)
(3)
(4)
(5)
  • All reactions are exothermic.
  • C is removed as gas.
  • Except C, all other impurities are removed as oxides and all these oxides float on the surface of the molten metal during refining of hot metal to steel.
  • Iron oxidation is unavoidable. Oxidation of Fe is loss in productivity; hence its oxidation must be controlled.
  • Oxygen must be dissolved to remove an impurity from the hot metal.

We begin with considering oxidation of an individual element and evolve the optimum conditions using thermodynamic principles.