Module 1:Steelmaking Fundamentals
  Lecture 6: Steel Making Reactions: Oxidation of Iron and Silicon
 

 

The equation 9 can be used to determine wt% O in steel at any temperature T, when  in slag is known.
When pure FeO is in contact with Fe;. We can determine  at saturation for different temperatures:


T (K)

1873

0.233

1923

0.285

We note that increase in temperature increases oxygen dissolved in molten iron.

The above values of dissolved oxygen correspond when pure FeO is in contact with Fe pure. In steelmaking FeO is present along with other oxides like calcium oxide, magnesium oxide, silica, manganese oxide etc, hence activity of FeO is influenced by other solute oxides. Thus
 
where  is activity coefficient and  mole fraction of FeO in slag,. depends on slag composition. In CaO--FeO system, as  ratio increases increases; physically it means that CaO replaces FeO from FeO.. The following expression is used to express :

(10)


Consider a slag with  = 0.5 ;  according to equation 10 is 0.31; [wt% O] in steel would be 0.072  as calculated by equation 9.

Few other equations are available; i.e.

(11)
(12)

The calculations are made on [wt% O] by equations 9, 11 and 12 at different temperatures using .


T (K)

1873

0.233

0.229

0.220

1923

0.285

0.280

0.268

There is a slight difference in the values of dissolved oxygen content in steel. But all equations suggest that increase in temperature increases dissolved oxygen in iron which is in contact with pure FeO. This calculation indicates that control of temperature is important to limit the dissolution of oxygen in molten iron.