Module 1: Structure of Ceramics
  A Brief Review of Bonding in Materials
 


1.2.3 Bonding, Bond Energy and General Remarks

 

Type
Bond Energy
Comments
Ionic

Large magnitude

(Large Tm, large E and small α )

Example: MgO – 1000 kJ / mol, Tm- 2800oC

Non-directional

(Typically Ceramics)

Covalent

Variable for materials such as Si, Ge

Large for Diamond (Carbon) and small for Bismuth

Typically Large Tm and large E

Example: Si - 450 kJ/mol; Tm- 1410oC

Directional

(Typically Semiconductors, Polymers and some Ceramics)

Metallic
Variable

Large: Tungsten (W)

Small: Mercury (Hg)

Moderate: Al: 68 kJ/mol, Tm~ 670oC

Non–directional (Metals)
Secondary

Smallest

Characterized by low Tm, low E and large α

Directional

Inter–chain (Polymer)

Inter–molecular

Symbols: Tm: Melting point, α: Coefficient of thermal expansion, E: Elastic modulus