more energy and is at slightly higher frequency.
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The O–H bands occur at higher frequency, sometimes as a sharp absorption at about 3600 cm-1 . More often, you will see a broad absorption at anywhere from 3500 to 2900 cm-1. This is because OH groups form strong hydrogen bonds that vary in length and strength. The sharp absorption at 3600 cm-1 is the non-hydrogen-bonded OH and the lower the absorption the stronger the H bond.