Module 3 : Coordination Chemistry

Lecture 5 : Valance Theory of coordination complexes and Crystal-field Theory

 

Octahedral complexes:

In an octahedral field those d orbital whose lobes are directed along the axis will experience greater interaction from the point charges placed in those directions. These are the dx2 −y2 and dz2 orbitals- the electron of these orbital will experience stronger repulsion from the point charges in the environment i.e. these orbitals will be destabilized & their energy will be raised to some extent.

But the remaining three orbital dxy, dxz and dyz have their lobes between the axes (45°) and will be less effected by the point charges in the environment i.e. these orbitals will be subject less electronic repulsion and to maintain the barycentre or center of gravity, energy of these orbitals will be lowered some extent.