Examples:
3.3.7.3 Peterson Reaction
The addition of a α -silylcarbanion to a carbonyl compound leads to the formation alkene by elimination of lithiumtrimethylsilanoate (Scheme 18).
Scheme 18
Examples:
3.3.7.4 Ramberg-Backlund-Reaction
α -Halogensulfone reacts with strong base to give an alkene (Scheme 19).
Scheme 19
3.3.7.4 Shapiro Reaction
Decomposition of a p -tosylhydrazone with two equiv of a strong base (generally methyllithium) gives alkene or vinyl lithium compounds (Scheme 20).
Scheme 20