Module 5 : Modern Characterization of materials

Lecture 32: Powder X - ray diffraction

 

Most of our powder diffractometers use the Bragg-Brentano parafocusing geometry.

  • A point detector and sample are moved so that the detector is always at 2q and the sample surface is always at q to the incident X-ray beam.
  • In the parafocusing arrangement, the incident- and diffracted-beam slits move on a circle that is centered on the sample. Divergent X rays from the source hit the sample at different points on its surface. During the diffraction process the X rays are refocused at the detector slit.
  • This arrangement provides the best combination of intensity, peak shape, and angular resolution for the widest number of samples.