Module 5 : Modern Characterization of materials

Lecture 32: Powder X - ray diffraction

Quantitative Phase Analysis

•With high quality data, you can determine how much of each phase is present
  • –must meet the constant volume assumption (see later slides)
•The ratio of peak intensities varies linearly as a function of weight fractions for any two phases in a mixture
  • –need to know the constant of proportionality
•RIR method is fast and gives semi-quantitative results
•Whole pattern fitting/Rietveld refinement is a more accurate but more complicated analysis