Chapter 2:Quantum Theory

Quantum Physics

To study this - we will review

  • Simple quantum mechanics
  • Energy band theory
  • Density of states for carriers
  • Recombination and generation of carriers
  • Carrier transport

Quantum Theory

Started in 1901 when Max Planck explained blackbody radiation.

Solid objects emit radiation when heated.

Black body radiation curves showing peak wavelengths at various temperatures:-

 

Fig.1.5

For more insight, play with Java Applets of Black body radiation from the following links:

  1. http://www.lon-capa.org/~mmp/applist/blackbody/ black.htm
  2. http://webphsics.davidson.edu/alummi/MiLee/java/_mjl.htm

Many attempts were made to explain the Black Body radiation pattern i.e, Rayliegh-Jeans, Wiens.

 

Fig.1.6

Finally Planck solved it.

Vibrating atoms in material could only radiate or absorb energy in discrete packets.

For a given atomic oscillator vibration at a frequency Hz. Planck postulated that the energy of the oscillator was restricted to quantized values.

and is the circular frequency

h = Planck's constant =

  One quantum of energy , where = Wavelength (m) and 'c' is the velocity of light in free space.

Bohr's theory of atoms

To explain why atoms when energized (heat, electric discharge) emit discrete spectral lines  , i = integer as shown in Fig.1.7

 

Fig.1.7

 

Bohr said that electrons in an atom move in well defined orbits, each orbit has a fixed energy level and angular momentum.

Hydrogen atoms, atomic No. = 1, and has only one electron

Angular momentum of this atom

= electron rest mass, = linear electron velocity

= radius of the orbit for a given n

Now at equilibrium, centrifugal force = electric force

              for n th orbit

Total energy

Light energy emitted by a Hydrogen atom when heated or excited

discrete in nature and equal to

                                                            

as shown in Fig .1.8

 

Fig.1.8