Module 1:Basics of energy balance
  Lecture 9: Energy balance and metal extraction
 


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Metal Extraction Principles

As   discussed in lecture 1, pyrometallurgical extraction of metals from natural oxide reserves involve the following steps:

  • Removal of oxygen from the valuable mineral.
  • Separation of metal from the gangue minerals.

For sulphide ore an additional step to convert sulphide into oxide is required. Several unit processes are employed to extract metal from ore by pyrometallurgical route. These are: roasting, matte smelting, reduction smelting, converting and refining. Different unit processes are combined to extract metal for example.

Production of metal     Combination of unit processes
Copper        Roasting +matte smelting +converting +refining  Flash smelting +converting +refining.
                                                        
Zinc & lead        Roasting +reduction smelting + refining
Nickel    Roasting +matte smelting + reduction smelting +refining.
Pig iron      Reduction smelting
Steel      Reduction smelting +refining.

Hydrometallurgical extraction is suitable for lean ores .here leaching followed by separation of metal from solution are the principal unit processes. Some examples of Hydrometallurgical extraction are

Copper:    Roasting +leaching +cementation+ electro wining 
Zinc:       Roasting +leaching +cementation+ electrolysis 
Aluminum:   Leaching + electrolysis
Magnesium:   Leaching + electrolysis
Titanium: Reduction smelting +leaching +chlorination +reduction by Mg