Module 4:Unit processes 2
  Lecture 39: Industrial furnaces
 


Exercise-III

Consider combustion of fuel oil with air to heat the furnace to a temperature at Fuel oil analyses 84% C 5% H 2% S and 9% incombustibles. Gross calorific value of fuel oil is 9500 kcal/kg. Determine GAH in each case when the furnace temperature T is (a) (b) (c) (d)

Assume complete combustion with the theoretical amount of air

Solution

Basis of calculation is 1 kg fuel. Reference state of in POC is liquid and the reference temperature is

First we have to calculate the amount of POC. Combustion is complete with theoretical amount of air, POC consists of and . We can calculate the amount of each constituent of POC by the Stoichiometry of the reaction as illustrated in the lectures on combustion (Lecture 9-11). We can calculate heat carried by each constituent of POC at each temperature by using mxCpxdT. The calculated values are given in the table

POC

Sensible heat (kcal) at T =1000K

Sensible heat (kcal) T=1100K

Sensible heat (kcal) T = 1200k

Sensible heat (kcal)T = 1400K

CO2

  560

  652

   746

  937

H2O

 209

  222

   235

 261

N2

1452

1675

1903

2346

Total

2161

2549

2884

3544

GAH

7339

6951

6616

5956


Increase in temperature from 1000K to 1400K decreases GAH by Decrease in GAH is followed by increase in fuel consumption in the same proportion.