Module 1: Steelmaking Fundamentals
  Lecture 8: Dephosphorization Reaction
 

From equation 16 one can determine the value of activity coefficient of  which
can lead to simultaneous removal of carbon and phosphorus.

Let us calculate the    when molten metal contains 2% C and 0.15% P and
temperature T=1773K. The mole fraction of in slag is 0.1.

(17)

  
        
We can calculate  and from equations 15 and 17. Substituting all the values
into equation 16 we get . We can also calculate  at temperatures 1673K and 1873K.
The results are given below

T(K)

1673

1773

1873

The calculations show:

  • Both decarburization and dephosphorization are possible simultaneously in presence of slag in
    which   has extremely low value.
  • Low temperature requires in slag to be higher than at high temperature.
    Thus low temperature is favourable.

References

  • A. Ghosh and A. Chatterjee; Ironmaking and steelmaking
  • R. Tupkary et.al. Modern methods of steelmaking
  • A.K.Chakrabarti: Steelmaking