Module 1: Structure of Ceramics
  Brief Review of Structure in Materials
 
       1.1.6 Crystal Systems
  • As you can see now, the choice of unit cell is not unique and we can define any unit cell of any shape as long it contains one lattice point.

  • However, as one starts defining various shapes, we come up with seven categories, called as crystal systems, in which all possible unit cells shapes would fit provided space filling criteria is fulfilled.

  • Seven crystal systems are shown below.

 

Crystal system and lattice parameters

Minimum symmetry elements

Cubic

a = b = c,

Four 3-fold rotation axes
 

Tetragonal

One 4-fold rotation (or rotation-inversion) axis
 

Orthorhombic

Three perpendicular 2-fold rotation (or rotation-inversion) axis
 

Rhombohedral

a = b = c

One 3-fold rotation (or rotation-inversion) axis
 

Hexagonal

One 6-fold rotation (or rotation-inversion) axis

Monoclinic

One 2-fold rotation (or rotation-inversion) axis

Triclinic

None

Figure 1.6 Seven crystal systems