Module 1 : Classical Thermodynamics

Lecture 1 : Review of Thermodynamics

Exceptions:

Table : 1.2 Symbols for Exceptional Properties

Parameter

Property

Traditional symbol

Temperature

Intensive property

T

Mass

Extensive property

m

Number of moles

Extensive property

n

Specific extensive properties, i.e., extensive properties per unit mass are intensive properties. For example: specific volume, specific energy, density, etc.
It may be worth mentioning here that cyclic integral of the differential of any thermodynamic property must be zero. For example,

However, change in volume between state points 1 and 2 is

Path and process

An operation in which one or more of the properties of a system changes is called a change of state. The sucession of states passed through during a change of state is called the path of the change of state.

The path of thermodynamic states that a system passes through as it goes from an initial state to a final state is known as the thermodynamic process.

Different thermodynamic processes are given in Table 1.3

Table : 1.3 Different Thermodynamic Processes

Sl No
Name of the process
Parameter Held Constant
Remarks
1 Constant pressure(Isobaric) p = constant v = (mR/P)T
2 Constant volume(isochoric) process V = constant p = (mR/V)T
3 Constant temperature (isothermal) process T = constant pV = constant
4 Polytropic process n pVn = constant
5 Adiabatic process no heat flow across the systemboundary pvγ = constant
6 Isoenthapic process h = constant h = constant