Exceptions:
Table : 1.2 Symbols for Exceptional Properties
Parameter |
Property |
Traditional symbol |
Temperature |
Intensive property |
T |
Mass |
Extensive property |
m |
Number of moles |
Extensive property |
n |
Specific extensive properties, i.e., extensive properties per unit mass are
intensive properties. For example: specific volume, specific energy, density,
etc.
It may be worth mentioning here that cyclic integral of the differential of
any thermodynamic property must be zero. For example,
However, change in volume between state points 1 and 2 is
Path and process
An operation in which one or more of the properties of a system changes is called a change of state. The sucession of states passed through during a change of state is called the path of the change of state.
The path of thermodynamic states that a system passes through as it goes from an initial state to a final state is known as the thermodynamic process.
Different thermodynamic processes are given in Table 1.3
Table : 1.3 Different Thermodynamic Processes
Sl
No |
Name
of the process |
Parameter
Held Constant |
Remarks |
1 | Constant pressure(Isobaric) | p = constant | v = (mR/P)T |
2 | Constant volume(isochoric) process | V = constant | p = (mR/V)T |
3 | Constant temperature (isothermal) process | T = constant | pV = constant |
4 | Polytropic process | n | pVn = constant |
5 | Adiabatic process | no heat flow across the systemboundary | pvγ = constant |
6 | Isoenthapic process | h = constant | h = constant |