Features of this migration
- • The carbocation may be produced by a variety of ways.
• Hydrogen can also migrate in this system.
• Aryl groups have a greater migratory aptitude than alkyl group or hydrogen due to the formation of lower-energy bridged phenonium ion.
• Rearrangements in bicyclic systems are common.
• The rearrangement is stereosepecific
• Two or more rearrangements may take place simultaneously.
Examples: