Module 2 : Systems under technological importance

Lecture 13 : Organic Light Emitting Diodes

 

Rules governing the fluorescence of metal chelates

(1) Paramagnetic metal ions : Essentially non-fluorescent

(2) Increasing atomic number : Fluorescence reduced

InQ3 < GaQ3<AlQ3

(3) Covalent nature of the metal-ligand bonding increased : Emission shifts to longer wavelength.