Module 2 : Systems under technological importance
Lecture 13 : Organic Light Emitting Diodes
Rules governing the fluorescence of metal chelates
(1) Paramagnetic metal ions : Essentially non-fluorescent
(2) Increasing atomic number : Fluorescence reduced
InQ3 < GaQ3<AlQ3
(3) Covalent nature of the metal-ligand bonding increased : Emission shifts to longer wavelength.