Module 7: "Surface Thermodynamics"
  Lecture 36: "Potential Energy"
 

 

If ψo1 = ψo2 = ψo we get:

(9.48)

Under Deryaguin approximation electrical potential energy of spherical particle can be written as

(9.49)

From equation (9.47) substituting value of GEL in equation (9.49) we have

where R is replaced by  for particles of different diameter. If ψo1 = ψo2 = ψo we get:

(9.50)

Fig. 9.5: Electric force between two particles with distance.

From above figure we see that for same type of potential on the two surface, FR will be repulsive for d> Dc but will be attractive for d< Dc.  To avoid the distortion of potential field, 2nd plate is kept where the potential of 1st plate is equal to that of 2nd plate.