Module 3 : Molecular physics and molecular structure
Lecture 34 : Term values of the electronic states of the molecule
 

Now we will carry out some examples of diatomic molecules to find out the ground state from its electronic configuration.

Closed shell configuration:

For any closed shell molecular electronic configuration, for example , there is no net orbital and spin angular momentum. So, L = 0 and S = 0. The term will be always,  state.

One unpaired electron:
Let us take the case of hydrogen molecular ion  
The electronic configuration (figure-34.3).

Figure 34.3

Bond order
= (no. of electrons in bonding orbital- no. of electrons in anti-bonding orbital) / 2
= (1-0) / 2 = ½ > 0. Molecular electronic state is stable.
Molecular term for the ground state is  

     (figure-34.4)

Bond order = ½ > 0.
Stable ground state will form.
Parity = g ´ g ´ u = u     Molecular term for the ground state is

Figure 34.4