Module 3 : Molecular physics and molecular structure
Lecture 27 : Understanding of Molecular Orbital
 

Let us take an example of oxygen molecule.
Oxygen atom is having electron configuration 1s22s22p4. So the oxygen molecule is having total of 16 electrons.

      
   

The figure-27.6 shows that for oxygen molecule, there are two unpaired electrons.

Figure-27.6

Bond order indicates the strength of a bond and is defined as
Bond order = (no. of electrons in bonding orbitals )/2
                        – (no. of electrons in the antibonding orbitals )/2
For oxygen, considering only the valence electrons (2p orbital)
Bond order = (8-4)/2 = 2. So the result is a double bond.
Bond order =1 (single bond); Bond order = 2 (double bond) e.t.c