Module 2 : Atomic Physics & Atomic Structure
Lecture 18 : Fine Structure : multi-electron atoms
 

2S + 1 is the known as multiplicity. Indicates the degeneracy of the level due to spin.
If S = 0    => multiplicity is 1: singlet term.
If S = 1/2 => multiplicity is 2: doublet term.
If S = 1    => multiplicity is 3: triplet term and so on.
In the following we will discuss the effect of spin-orbit interaction on terms to terms transitions.

Singlet levels

Selection Rules :