Module 1:Basics of energy balance
  Lecture 8:Thermo chemistry applications in metal extraction
 

 

Problem of 5:  Heat of formation of compound

Given the following heats of formation





.

Required the molar heat of formation of  from   and

Now you can try this problem and get heat of formation of

Problem 6: Production of silicon carbide

Calculate the heat of the reaction for production of silicon carbide:

 

The reactants and products are at 1973 K

Components

 (J/g.mol)

Cp (J/g.mol  K)

SiO2

   -841386

46.945 + 34.309 x 10-3T-11.297 x 105 T – 2)

C

    --------

17.154 + 4.268 x10

SiC

   117208

109.266 + 14.67 x 10-3T – 39.468 x 105T-2 )

CO

   112352

28.409+4.1x10-3 T-0.460 x 105T-2 )

Problem of   this type are illustrated. Practice it to calculate heat of reaction