Module 1:Basics of energy balance
  Lecture 7: Thermochemistry: Illustration
 

 

Do yourself – ii

For a solid silver, the molar heat capacity at constant pressure

 

Find heat content of silver at 1235K.

, melting print of .

Answer: .


Illustration iii

Find the enthalpy change at 900k for the reaction

 

Component

 Cp J/mol K.

CaO(s)

634.3

49.62+(4.52x10-3T)-(6.95x105T-2)

CO2(g)

393.5

44.14+(9.04x10-3T)-(8.54x105T-2)

CaCO3(s)
1206.7

104.52+(21.9 2x10-3T)-(25.94x105T-2)



  for reaction 1.

 

 

 

  joules.

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Do yourself – iii

Calculate enthalpy of copper at 950K and the enthalpy increment for heating copper from 298 K to 950K
.
 

Enthalpy increment

 

Ans. enthalpy  of  since  for Cu is zero.