Module 3: Unit Processes 1
  Lecture 29: Exercises in material balance in Iron-making
 



Exercise V


The input and output of a blast furnace are:

Iron ore:  

Coke:

Limestone  

Pig Iron:  

Top Gas  

Assume some iron is lost as  in slag. Per ton of pig iron there is 1.82 tons of ore is used
Determine:

a) Amount of coke/ton of pig iron.

b) Composition of slag/ton of pig iron.

c) Perform oxygen balance and comment.

Solution:

Carbon balance:

Carbon from coke + carbon from  and  in pig iron + carbon in gases
Substituting values give coke =1000.37 kg

Composition of slag: It consists of .

 in slag can be calculated from Si balance  in slag can be obtained from  . Similarly,  and  balance can be done to obtain respective oxides.

Amount of slag = 742.78 kg    


SiO2
percent
40
Al2O3
7.5
MnO
1.8
CaS
1.1
CaO
36.0
MgO
0.5
FeO
13.12

Amount of top gas  pig iron

Amount of air (from   balance)    (c)

Oxygen balance:

Oxygen balance can be made air to compare answer in c.

 in top gas = 50.71 kg moles.

 in top gas is from air and oxygen released from various oxides.


  from air = 50.71 - released from oxides

During BF iron making:  are reduced and relesase oxygen. Decomposition of  and  also releases oxygen.

Oxygen released = 18.057 kg moles.

 from air = 32.653 kg moles

Blast volume = 3483 m3

This volume compases very well with that determined form   balance.