Module 3: Unit Processes 1
  Lecture 25: Matreial balance in imperial smelting process
 

 
Materials balance

Basis: 1000 kg sinter.

The reduction equations for  and  can be written by using the moles of  and participating in the reaction and taking into account  ratio in the exit gas is 2:1. This approach will directly give the moles of products. However, other approaches may also be used

 

Kg moles

Zn(v) =

6.173

Pb(l) =

0.897

CO2 =

7.070

CO =

14.140

N2 =

39.875

 

The exit gas amount as determined from Zn vapour balance is 88.186 kg moles.

The amount of  exit gas as determined from the stoichiometric reduction equation is equal to  

Difference  is due to excess  and excessin the flue gas. Thus the revised composition of exit gas is

 

Kg moles

Zn(v) =

6.173

O2

4.40

CO2 =

7.070

CO =

14.140

N2 =

56.405



Liquid slag contains and 

.