Module 3: Unit Processes 1
  Lecture 21: Matte smelting; material balance

Problem2

A copper smelter smelts the ore of the following composition given below in weight percent:
. Limestone of composition
 and  is one-fifth of the weight of the ore. The coke is  of the ore and its ultimate analysis is . During smelting  of the total sulphur charged is oxidized as . The analysis of dry flue gas (In Volume %) No copper is lost in slag and ignore the flue dust.

Determine (for 1000kg ore):

a) The weight of matte and its grade,

b) Weight and composition of slag,

c) Volume of gases (dry), calculated from sulphur and carbon content,

d) Cubic meter of air.

Solution:

Basis is 1000kg ore.

Matte consists of .Cu2S+ Fes

Performing S balance and  balance one can find S combined with  and then amount of FeS

Weight of matt  and its Grade is

Slag consists of  and , since all does not enter into matte.
One can find weight of each component

Weight of slag is

SiO2
41.6%
Al2O3
5.5%
CaO
20.7%
FeO
32.2%


Volume of gases

On performing S and C balance

.