Module 1: Steelmaking Fundamentals
  Lecture 9: Refractory Materials
 


Why required?

  • To minimize heat losses from the reaction chamber
  • To allow thermal energy dependent conversion of chemically reactive reactants into products because metallic vessels are not suitable.

In steelmaking, the physico- chemical properties of the following phases are important:

Slag:    Mixture of acidic and basic inorganic oxides like etc.; temperature             varies in between .

Molten steel: Iron containing carbon, silicon, manganese, phosphorous, tramp elements, non metallic                       inclusions, dissolved gases like nitrogen, oxygen and hydrogen and different alloying                       elements like  etc.; temperature  

Gases:   containing solidparticles of  etc.; temperature
                        .

 The above phases are continuously and constantly in contact with each other and are in turbulent motion

Compounds

Melting point

MgO (pure sintered)

2800

CaO(limit)

2571

Si C pure

2248

MgO (90-95%)

2193

Cr2O3

2138

Al2O3(pure sintered)

2050

Fireclay

1871

SiO2

1715

Kaolin (Al2O3. SiO2)

1816

Chromite (FeO. Cr2O3)

2182

.