3) Problems on deoxidation (Refer lecture 24)
a) Calculate the time required to float deoxidation product through a 2 meters steel bath height from the following data:
Density of liquid steel and and viscosity of liquid steel
Size of deoxidation product = 10micron 50 micron and 100 micron
Repeat the calculation when de oxidation product is silica and its density is
Interpret the result and get a feel about the importance of size of de oxidation products on velocity.
b) Aluminum, titanium and zirconium are the strongest deoxidizers compared with manganese. Deoxidation with either aluminium or zirconium or titanium shows a minimum solubility of oxygen in steel. Determine the expression to calculate the value of Al in weight percent at minimum oxygen content in Fe-Al-O system
Given: and
Let us consider the following reaction;
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(1) |
Assume activity of alumina, , since it is pure,
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(2) |
Substitute and and expression for and in equation 2. Differentiate the expression 2 with respect to get
For the minima and we get
The readers may substitute the values of the interaction parameters to get a feel of the value of Al and to understand the role of interaction parameters in calculations.
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